mass of water (g) 
volume of water (mL) 
238.3  239.0 
499.8  501.3 
846.3  848.8 
1010.0  1013.0 
What is the pattern in this data? Increasing the mass of the sample seems to increase the volume of the sample by roughly the same amount; doubling the mass doubles the volume. If you divide the volume by the mass for each of the four points, you get 1.003 mL/g every time. For this experiment, water has a constant volume per gram. To make the pattern plain, you can graph the volume as a function of mass:
Take a ruler and draw the best straight line through the data points. The slope (steepness) of the line is telling us how fast volume changes for a particular change in mass. The slope happens to be 1.003 mL/g. We can summarize ALL of the data using a simple equation:
where V is the volume of water in mL, m is the mass, and c is the proportionality constant; 1.003 mL/g in this case. We can say that volume of water is directly proportional to mass of water.
The direct proportionality relation between volume and mass is often written in physical sciences this way:
The symbol means "is directly proportional to" or "is equal to some constant times". This is a useful way to summarize the relationship between the two variables if we don't know (or don't care) what the actual value of the proportionality constant is. Saying V m is equivalent to saying any of the following:
V/m is a constant.
V = c m, where c is some constant.
V_{1}/m_{1} = V_{2}/m_{2} where 1 and 2 are any pair of data points.
This last statement allows you to predict the value of any one measurement given the other three.
Exercise 1. Using the symbols given, write the following relationships in as many ways as you can. Sketch a graph of the relationship. What is the slope of the line on the graph?
volume of gas (mL) 
temperature of gas (°C) 
101  8.4 
231  370.7 
416  886.3 
892  2213.0 
Is the volume of the balloon zero at 0°C? To see, we can extrapolate the best straight line that can be drawn through all of the data points to 0°C:
It seems that the volume of the balloon around 0°C will be around 22.5 mL. So it is incorrect to write
or
because the volume isn't zero when when the celsius temperature is zero. We can write
where b is the volume at the point where the extrapolated line hits the volume axis (about 22.4 mL in this case). b is sometimes called the yintercept of the line.
As with proportionality relations, c is a constant that is just the slope of the line. It's possible to have negative slopes, which indicate that the variable on the yaxis decreases as the variable on the xaxis increases.

It looks like doubling the volume cuts the pressure to one half its original value. Multiplying the pressure and volume together for each point, we get the same number (22.4_{6} mL atm) every time. The relationship between pressure P and volume V can be written
or
or
When two variables are related this way, they are said to be inversely proportional.
Copyright © 19972005 by Fred Senese
Comments & questions to fsenese@frostburg.edu
Last Revised 07/25/05.URL: http://antoine.frostburg.edu/chem/senese/101/gases/printpatterns.shtml