![]() | Vocabulary |
insoluble![]() oxidation ![]() oxidizing agent ![]() permanganate ![]() reduction ![]() |
Permanganate itself is a deep purple color (almost black). The brown stain develops when permanganate decomposes into crystalline manganese dioxide on the skin or fabric surface:
4 MnO4-(aq) + 4 H+(aq) = 3 O2(g) + 2 H2O() + 4 MnO2(s)
MnO2(s) + 4 HCl(aq) = MnCl2(aq) + Cl2(aq) + 2 H2O()
Curiously, permanganate's oxidizing power makes it very useful for removing stains. Permanganate oxidation breaks the molecules of large, highly colored substances into smaller pieces. The excess permanganate is then removed chemically or by quickly rinsing.
For example, book collectors remove stains from old paper by washing the paper with a weak solution of permanganate; a rinse of sulfurous acid is used to remove the permanganate before it locks into the paper fibers and turns it brown [1]. The same trick can be used to remove indelible inks from concrete [2]. Photographers use permanganate to bleach stains caused by certain developing chemicals.
Copyright © 1997-2010 by Fred Senese
Comments & questions to fsenese@frostburg.edu
Last Revised 02/23/18.URL: http://antoine.frostburg.edu/chem/senese/101/redox/faq/print-permanganate-stains.shtml