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Chemical reactions are often classified to highlight patterns in chemical behavior. In some cases, categorizing a reaction can allow its products to be predicted.
Many chemical reactions fall into one of four broad classes: rearrangement, combination, decomposition, and displacement.
- Combination reactions build a compound from simpler compounds or elements.
- General form: A + B
C
- Recognition: Usually a single product and several reactants
- Synonyms: synthesis
- Examples
C2H4(g) + H2O(g) C2H5OH(g)
H2(g) + ½ O2(g) H2O(l)
- Decomposition reactions break a compound into simpler fragments.
- General form: C
A + B
- Recognition: Usually a single reactant and several products
- Examples
H2CO3(aq) H2O(l) + CO2(g)
CaCO3(s) CaO(s) + CO2(g)
2NH4NO3(s) 2N2(g) + 4H2O(g) + O2(g)
2 H2O(l) 2 H2(g) + O2(g)
- Rearrangement reactions making and breaking bonds within a compound.
- General form: A
B
- Recognition: reactant and product have same molecular formula but different structural formulas
- Synonyms: isomerization
- Displacement reactions involve replacement or swapping of parts of a compound.
- General forms
- single displacement: A + BC
AB + C
- double displacement: AB + CD
AD + BC
- Features
- # of reactants is usually equal to the # of products
- atoms or ions migrate from one compound to another
- Synonyms: double displacement reactions are sometimes called "metathesis" reactions
- Examples
Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g)
Mg(s) + CuCl2(aq) MgCl2(aq) + Cu(s)
NaOH(aq) + HCl(aq) H2O(l) + NaCl(aq)
BaCl2(aq) + Na2SO4(aq) = BaSO4(s) + 2 NaCl(aq)
These additional categories include many important chemical reactions. Learn to recognize them.
- Neutralization reactions: one compound acquires H+ from another
- Features
- usually double displacement reactions (but not always)
- one reactant must be an acid (have detachable H+ ions)
- one reactant must be a base (accept H+ taken from the acid)
- water is a product if the base is a hydroxide
- Synonyms: acid-base reaction, proton transfer reaction
- Examples
H2SO4(aq) + 2 NaOH(aq) Na2SO4(aq) + 2 H2O(l)
KOH + HC2H3O2(aq) H2O(l) + KC2H3O2(aq)
NH3(aq) + HCl(aq) NH4Cl(aq)
- Precipitation reactions: solid product is formed in a liquid or gaseous environment.
- Features
- usually displacement reactions that form an insoluble ionic compound
- Examples
AgNO3(aq) + NaCl(aq) = AgCl(s) + NaNO3(aq)
SrCl2(aq) + Na2SO4(aq) = SrSO4(s) + 2 NaCl(aq)
- Redox reactions occur when one compound acquires electrons from another
- Features
- at least one reactant loses electrons
- at least one reactant gains electrons
- Examples
- combustion reactions (fuel reacting with oxygen)
2 C2H6(g) + 7 O2(g) 4 CO2(g) + 6 H2O(g)
- combination of elements
2 Na(s) + Cl2(g)
2 NaCl(s)
- displacement of hydrogen from water or acids
2 Na(s) + 2 H2O(l)
2 NaOH(aq) + H2(g)
Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g)
- displacement of metal ions from solution
Mg(s) + CuCl2(aq) MgCl2(aq) + Cu(s)
Zn(s) + 2 AgNO3(aq) Zn(NO3)2(aq) + 2Ag(s)
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