It is possible to have isolated H+ ions in the gas phase.
But if a free hydrogen ion encounters a water molecule, it attacks the unshared electron pairs on the oxygen in the water molecule and forms a hydronium ion, H3O+. The chemical bond that forms between the water and hydrogen ion is covalent and very strong. In an aqueous solution, essentially all of the H+ exists as H3O+.
When people write "H+(aq)" in a chemical equation, it's understood that they really mean "H3O+(aq)". Writing hydrogen ions rather than hydronium ions makes neutralization equations a little easier to read and balance.
Author: Fred Senese senese@antoine.frostburg.edu