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Home :Glossary

Glossary: The quantum theory

The displacement of a wave from zero. The maximum amplitude for a wave is the height of a peak or the depth of a trough, relative to the zero displacement line.

constructive interference. Compare with destructive interference*.
When the peaks and troughs of two interfering* waves match, the amplitudes add to give the resultant wave a higher amplitude.

destructive interference. Compare with constructive interference*.
When the peaks of one wave match the troughs of another, the waves interfere* destructively. The amplitudes* of the interfering waves cancel to give the resultant wave a lower amplitude.

diffraction. diffract. Compare with effusion*.
The ability of a wave to bend around the edges of obstacles or holes. The effect is most noticeable when the obstacle or hole is comparable to the size of the wavelength*.

electromagnetic radiation. electromagnetic wave.
A wave* that involves perpendicular oscillations in the electric and magnetic fields, moving at a speed of 2.99792458×108 m/s in a vacuum away from the source. gamma rays*, x-rays*, ultraviolet light*, visible light*, infrared radiation*, and radio waves* are all electromagnetic waves.

frequency. (nu) Compare with wavelength*.
The number of cycles of a wave that move past a fixed observation point per second. The SI unit of frequency is the Hertz* (Hz).

gamma rays. (gamma-rays) gamma radiation.
A very high energy form of electromagnetic radiation*, typically with wavelengths* of less than 3 pm. Gamma rays are produced by certain nuclear decay processes, and are used to sterilize food.

Hertz. (Hz, s-1) frequency.
The SI unit of frequency*, equal to one cycle of the wave per second (s-1).

infrared radiation. (IR) infrared.
Electromagnetic radiation* with wavelength* longer than visible light but shorter than that of microwaves*. Infrared radiation is produced by hot objects; absorption of infrared radiation causes chemical bonds to vibrate.

interference. interfering. Compare with constructive interference* and destructive interference*.
The amplitudes* of waves* moving into the same region of space add to produce a single resultant wave. The resultang wave can have higher or lower amplitude than the component waves. See constructive interference* and destructive interference*.

microwave. microwave radiation.
Electromagnetic radiation* with wavelength* between 3 mm and 30 cm.

momentum. (p)
Momentum is a property that measures the tendency of a moving object to keep moving in the same direction. Increasing the speed of an object increases its momentum, and a heavy object will have more momentum than a lighter one moving at the same speed. For a particle with mass m and velocity v, the momentum of the particle is mv.

A point, region, or surface where the amplitude* of a standing wave is zero. The probability of finding an electron at an orbital* node is zero.

phase. in phase; out of phase; wave phase.
1.A phase is a part of a sample of matter that is in contact with other parts but is separate from them. Properties within a phase are homogeneous (uniform). For example, oil and vinegar salad dressing contains two phases: an oil-rich liquid, and a vinegar-rich liquid. Shaking the bottle breaks the phases up into tiny droplets, but there are still two distinct phases. 2. In wave motion, phase is the fraction of a complete cycle that has passed a fixed point since the current cycle began. The phase is often expressed as an angle, since a full cycle is 360^deg; (2 pi). Two waves are "in phase" if the peaks of one wave align with the peaks of the other; they are "out of phase" if the peaks of one wave align with the troughs of the other.

photoelectric effect.
Ejection of electrons from an atom or molecule that has absorbed a photon* of sufficient energy. The photoelectric effect is the operating principle behind "electric eyes"; it is experimental evidence for particle-like behavior of electromagnetic radiation*.

An electron* ejected from an atom or molecule that has absorbed a photon*.

photon. (hnu) quantum; quanta.
A discrete packet of energy associated with electromagnetic radiation. Each photon carries energy E proportional to the frequency* nu of the radiation: E = hnu, where h is Planck's constant*.

Planck's constant. (h)
A proportionality constant that relates the energy carried by a photon* to its frequency*. Planck's constant has a value of 6.6262 × 10-34 J s.

quantum. quanta.
A discrete packet of energy.

quantum mechanics. quantum theory.
A branch of physics that describes the behavior of objects of atomic and subatomic size.

quantum number.
Indices that label quantized energy states. Quantum numbers are used to describe the state of a confined electron, e. g. an electron in an atom.

ultraviolet light. ultraviolet; ultraviolet radiation; ultraviolet region; UV.
Electromagnetic radiation* with wavelength longer than that of x-rays* but shorter than that of visible light*. Ultraviolet light can break some chemical bonds and cause cell damage.

uncertainty principle. Heisenberg's uncertainty principle; Heisenberg principle; indeterminancy; indeterminancy principle.
The exact momentum and exact location of a particle cannot be specified. Werner Heisenberg stated that the product of uncertainties in location and momentum measurements can never be smaller than h/4pi, where h is Planck's constant*.

visible light.
Visible light is electromagnetic radiation* with a wavelength* between 400 and 750 nm.

wavefunction. (psi)
A mathematical function that gives the amplitude* of a wave as a function of position (and sometimes, as a function of time and/or electron spin). Wavefunctions are used in chemistry to represent the behavior of electrons bound in atoms or molecules.

The distance between adjacent peaks (or adjacent troughs) on a wave*. Varying the wavelength of light changes its color; varying the wavelength of sound changes its pitch.

An oscillating motion that moves outward from the source of some disturbance (ripples running away from a pebble tossed in a pond). Waves transmit the energy of the disturbance away from its source.

A very high energy form of electromagnetic radiation* (though not as high energy as gamma rays*). X-rays typically have wavelengths from a few picometers up to 20 nanometers. X-rays easily penetrate soft tissue, which makes them useful in medical imaging and in radiation therapy.

x-ray diffraction pattern.
Interference patterns created by x-rays as they pass through a solid material. Studying x-ray diffraction* patterns gives detailed information on the three-dimensional structure of crystals, surfaces, and atoms.

x-ray spectrum. x-ray spectra.
A set of characteristic x-ray* frequencies* or wavelengths* produced by a substance used as a target in an x-ray tube*. Each element has a characteristic x-ray spectrum, and there is a strong correlation between atomic number* and the frequencies of certain lines in the x-ray spectrum.

x-ray tube.
A cathode ray tube that focuses energetic streams of electrons on a metal target, causing the metal to emit x-rays*.

zero point energy.
A minimum possible energy for an atom or molecule predicted by quantum mechanics*. Electrons stay in motion and bonds continue to vibrate even at absolute zero* because of zero point energy.

General Chemistry Online! The quantum theory

Copyright © 1997-2010 by Fred Senese
Comments & questions to fsenese@frostburg.edu
Last Revised 02/23/18.URL: http://antoine.frostburg.edu/chem/senese/101/quantum/glossary.shtml